Nitrogen-doped, FeNi alloy nanoparticle-decorated graphene as an efficient and stable electrode for electrochemical supercapacitors in acid medium
نویسندگان
چکیده
Nitrogen-doped graphene decorated by iron-nickel alloy is introduced as a promising electrode material for supercapacitors. Compared to pristine and Ni-decorated graphene, in acid media, the introduced electrode revealed excellent specific capacitance as the corresponding specific capacitance was multiplied around ten times with capacity retention maintained at 94.9% for 1,000 cycles. Briefly, iron acetate, nickel acetate, urea, and graphene oxide were ultrasonicated and subjected to MW heating and then sintered with melanin in Ar. The introduced N-doped FeNi@Gr exhibits remarkable electrochemical behavior with long-term stability.
منابع مشابه
Cost Effective and Scalable Synthesis of MnO2 Doped Graphene in a Carbon Fiber/PVA: Superior Nanocomposite for High Performance Flexible Supercapacitors
In the current study, we report new flexible, free standing and high performance electrodes for electrochemical supercapacitors developed througha scalable but simple and efficient approach. Highly porous structures based on carbon fiber and poly (vinyl alcohol) (PVA) were used as a pattern. The electrochemical performances of Carbon fiber/GO-MnO2/CNT supercapacitors were characteriz...
متن کاملAn Electrochemical Investigation of Nano Cerium Oxide/Graphene as an Electrode Material for Supercapacitors
In this paper, the effect of cationic and anionic ion sizes on the charge storage capability of graphene nanosheets is investigated. The electrochemical properties of the produced electrode are studied using cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) techniques in 3M NaCl, NaOH, and KOH electrolytes. Scanning electron microscopy (SEM) is used to characterize the mi...
متن کاملNitrogen and Phosphorous Co-Doped Graphene Monolith for Supercapacitors.
The co-doping of heteroatoms has been regarded as a promising approach to improve the energy-storage performance of graphene-based materials because of the synergetic effect of the heteroatom dopants. In this work, a single precursor melamine phosphate was used for the first time to synthesise nitrogen/phosphorus co-doped graphene (N/P-G) monoliths by a facile hydrothermal method. The nitrogen ...
متن کاملOne –step synthesis of PdCo alloy nanoparticles decorated on reduced grahene oxide as an Electro-catalyst for Oxygen Reduction Reaction in Passive Direct Methanol Fuel Cells
We report a Pd-Co (3:1)/graphene oxide (Pd3Co /GO) catalyst through a one-step strategy. GO is synthesized from graphite electrodes using ionic liquid-assisted electrochemical exfoliation. Controllable GO-supported Pd3Co electrocatalystis then was reduced by ethylene glycol as a stabilizing agent to prepare highly dispersed PdCo nanoparticles on carbon graphene oxide to be used as oxygen reduct...
متن کاملNitrogen-doped reduced graphene oxide electrodes for electrochemical supercapacitors.
Herein we use Nitrogen-doped reduced Graphene Oxide (N-rGO) as the active material in supercapacitor electrodes. Building on a previous work detailing the synthesis of this material, electrodes were fabricated via spray-deposition of aqueous dispersions and the electrochemical charge storage mechanism was investigated. Results indicate that the functionalised graphene displays improved performa...
متن کامل